chemistry·NCERT Class 12·Coordination Compounds

Coordination Complex & CFT

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[Fe(H₂O)₆]³⁺ is pale yellow but [Fe(CN)₆]³⁻ is deep red. The difference? Strong vs weak field ligands change how d orbitals split — and what colour light gets absorbed.

CFSE = crystal field stabilisation energy; larger Δ = more stable complex.
Colour: complex absorbs a complementary colour to the one seen.